A 2.0 L kettle contains 116 g of boiler scale (CaCO3). How many times would the kettle have to be completely filled with distilled water
to remove all of the deposit at 25 ec, of CaCO3 = 87x
Answers
Answer:
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Explanation:
From Ksp you can calculate the solubility of CaCO3.
In dissociation of one CaCO3 molecule one calcium ion and one carbonate ion are formed:
CaCO₃←→ Ca²⁺ + CO₃²⁻
so the ion concentrations are equal to the apparent concentration of dissolved calcium carbonate
[Ca²⁺] = [CO₃²⁻] = [CaCO₃]
At maximum solubility ion concentrations satisfy solubility product:
Ksp = [Ca²⁺] · [CO₃²⁻]
Hence
Ksp = [CaCO₃]²
<=>
[CaCO₃] = √Ksp
= √8.7×10-9
= 9.237×10-5 M
Multiply by molar mass to get the maximum soluble mass per unit volume:
ρ(CaCO₃) = [CaCO₃] · M(CaCO₃)
= 9.237×10-5mol/L · 100.087 g/mol
= 9.335×10-3g/L
So the minimum amount of water needed to dissolve 116g is
V = 116g / 9.335×10-3g/L = 12,426L