Chemistry, asked by gurpreetsingh000721, 1 year ago

A 50 ml Sol of pH = 1 is mixed with 50 ml sol of pH =2 what will be the pH of mixture

Answers

Answered by shrutibohra
3

Hello Dear.

Given conditions ⇒

In First Case,

Volume of the solution(V₁) = 50 mL.

pH = 1

∴ Concentration of H⁺ (M₁) = 10⁻¹

[∵ pH is less than 7, ∴ Solution is acidic.]

In Second Case,

Volume of the solution(V₂) = 50 mL.

pH = 2  [It is also acidic]

∴ Concentration of H⁺ (M₂) = 10⁻²

Now, Volume of the Final Solution(V) = V₁ + V₂

 = 50 + 50

 = 100 mL.

Since, both the solution above have the pH less than 7, i.e., both are acidic.

∴ MV = M₁V₁ + M₂V₂ 

⇒ M × 100 = 10⁻¹ × 50 + 10⁻² × 50

⇒ 100 M = 5 + 0.5

⇒ M = 5.5/100

⇒ M = 5.5 × 10⁻²

∴ Concentration of the H⁺ in the Final solution (or Mixture) is 5.5 × 10⁻².

Now, Using the Formula,

pH = -log [H⁺]

pH = -log[5.5/100]

pH = - log5.5 + log100

[∵ log(a/b) = loga - logb]

pH = log 100 - log 5.5

pH = 2 - log 5.5

[∵ log 100 = 2]

∴ pH = 2 - 0.74 

[∵ log 5.5 = 0.74]

∴ pH = 1.26

Hence, the pH of the Final solution (or Mixture) is 1.26.

Hope it helps.

.

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