a) Explain how to prepare 25 liters of a 0.10 M BaCl2 solution, starting with solid BaCl2.
b) Specify the volume of the solution in (a) needed to get 0.020 mol of BaCl2.
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Answer:
Concentration of KCl = 80g/L
⇒ 80 g of KCl is present in 1L of solution.
Concentration of KCl in MOLARITY is M₁ = 80/74.5 = 1.0738M
KCl → K+ + Cl- ⇒ [KCl] = [Cl-]
Concentration of Cl- in MOLARITY is M₁ = 80/74.5 = 1.0738M
BaCl2 → Ba2+ + 2Cl-
Let concentration of BaCl2 be x molar
⇒ [Cl-] = 2times [BaCl2] as two moles of Cl- is produced from 1 mole of BaCl2
It is given concentration of Cl- does not change.
[Cl-] = 1.0738M ⇒ [BaCl2] = 1.0738/2 = 0.5369M
By molarity equation ,
MOLARITY = Given mass/(molar mass * volume (L))
Given mass = 0.5369*208.5*250/1000 = 27.98 ==== 27.92g ( molar mass = 208.5g,
volume = 250/1000 L)
Explanation:
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