a hydrocarbon contains 10.5 gm of carbon per 1 gm of hydrogen. At 127°C temperature and 1 atm pressure, the vapour weight of the hydrocarbon is 2.8 gm. Determine the molecular formula of the compound
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As we know,
PV=nRT=wM/RT
or 1= 2.8/M ×0.0821×400
or M=91.95≈92
Let the formula be C a H b
.
So 12a+b=92b
12a
=10.5(given)
11.5b=92
or b=8
∴ a=7
Therefore, the formula is C
7
H
8
.
molar mass = 12*7+1*8 = 92gm/mole
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