A man went door to door posing as a goldsmith. He promised to bring back the glitter of old and dull gold ornaments. An unsuspecting lady gave a set of gold bangles to him which he dipped in a particular solution. The bangles sparkled like new but their weight was reduced drastically. The lady was upset but after a futile argument the man beat a hasty retreat. Can you play the detective to find out the nature of the solution he had used?
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The man had used the solution of aqua-regia is a mixture of nitric acid and hydrochloric acid, optimally in a molar ratio of 1:3. Aqua regia is a yellow-orange fuming liquid. Aqua regia was so named because it can dissolve the noble metals gold and platinum. After dipping the gold ornaments in it the outer layer of gold gets dissolved and the inner shiny layer appears.
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He must have dipped the gold metal in the solution of aqua regia − a 3:1 mixture of conc. HCl and conc. HNO3. Aqua regia is a fuming, highly corrosive liquid. It dissolves gold in it. After dipping the gold ornaments in aqua regia, the outer layer of gold gets dissolved and the inner shiny layer appears. That is why the weight of gold ornament reduced.
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