A metallic element exists as a cubic lattice each edge of the cubic lattice is 2.88 amstrong the density of the metal is 7.2g/cc . How many unit cell are there in 100g of metal .
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Assuming that it is a simple cubic lattice the effective number of atoms per unit cell (Z)=1
Atomic mass of the element is A
Avogadro's number N = 6.022*10^23
Edger length a = 2.88*10^(-8)cm
Density d = 7.20 g/cc
now
d=\frac{Z*A}{N* a^{3} } i.e. 7.2= \frac{1*A}{(6.022* 10^{23})*(2.88* 10^{-8}) ^{3}} i.e A = 103.57
so
mass of one atom ≡ 1 unit cell
i.e. 103.57u ≡ 1 unit cell
or 103.57 * 1.667 * 10^(-24) g ≡ 1 unit cell
or 100 g metal⇒ \frac{100}{103.57*1.667* 10^{-24} } =5.792* 10^{23} number of unit cells
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