A reaction occurs spontaneously if
(a) TΔS < ΔH and both ΔH and ΔS are + ve
(b) TΔS > ΔH and ΔH is + ve and ΔS is - ve
(c) TΔS > ΔH and both ΔH and ΔS are + ve
(d) TΔS = ΔH and both ΔH and ΔS are + ve
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A reaction occurs spontaneously if (c) TΔS > ΔH and both ΔH and ΔS are + ve.
Explanation:
- When a reaction is spontaneous, then the Gibbs free energy is negative.
- The Gibbs free energy is given by the formula:
- ΔG = ΔH - TΔS
- When the value of ΔH and ΔS are positive then TΔS > ΔH from which the value of ΔG is negative.
- If the value of ΔH = + ve and ΔS is - ve, the Gibbs free energy results in positive which is a non-spontaneous process.
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