[Ag'l'
59V
0.130
(0.0001)
log
3.17 V- 0.21V - 2.96 V.
K
the circuit in Daniell cell (Fig. 3.1) is closed then we note that the reaction
Zn(s) + Cu²+ (aq) → Zn?"(aq) + Cu(s)
(3.1)
takes place and as time passes, the concentration of Zn2 keeps
1 increasing while the concentration of Cu2 keeps on decreasing
the same time voltage of the cell as read on the voltmeter keep
decreasing. After some time, we shall note that there is no chang
the concentration of Cu” and Zn2+ ions and at the same tim
Itmeter gives zero reading. This indicates that equilibrium has be
cained. In this situation the Nernst equation may be written as
2.303RT (Zn)
0 = Ecom
Elcem
log
(cell)
2F
Cu² |
2.303RT (Zn)
or ECC
log
ICM2+1
(ce 11
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