Along toluene,benzene,benzanoic acid and nitrobenzene,which is most reactive electrophilic nitration
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Benzoic acid
Explanation: The (-COOH) group on benzene in benzoic is Electron Donating group(EDG) by positive resonance (+R)which is why benzoic acid is electron rich...For this,an electron deficient species will tend to attack on it more easily for electrons.
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