An alkane on complete combusion with O2 shows 50% of volume contraction. Molecular formula of alkane is-
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General equation for combustion :CxHy + (x+y/4)O2 → xCO2 + y/2H2OAccording to question :(x+(y/4))/x = 7/4Solving the equation we obtain:4x + y = 7x ory=3xy/x = 3/1Thus the alkane is of the type:CxH3xGaseous alkanes are CH4 , C2H6 , C3H8 ,C4H10 only and only gaseous alkane with formula of this type is C2H6.
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The formula for alkaline is 2 / 3n + 1 x no2. When you put across, you need to find n in this equation. It comes to 5 = 2 / 3n + 1 x 25.
n will be equal to 3. And then the milecular formula for alkane comes to C3H8
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