An impure sample of Calcium carbonate contains 80% pure calcium carbonate. 25g of impure sample reacted with excess of hydrochloric acid.Calculate the volume of carbon dioxide at NTPobtained from this sample.
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The mass of pure Calcium carbonate is :
80/100 × 25 = 20g
Equation for the reaction is :
CaCO₃ (s) + 2HCl (aq) —> CaCl₂(s) + CO₂(g) + H₂O(l)
The mole ratio of Calcium carbonate and the CO₂ liberated is 1 : 1
Moles of Calcium carbonate = mass of calcium carbonate / molar mass
Molar mass of Calcium carbonate = 100
Moles = 20/100 = 0.2 moles
Moles of CO₂ = 0.2 moles
Molar gas volume at NTP is :
1 mol = 22.4 litres
0.2 moles =?
0.2 × 22.4 = 4.48 litres
CO₂ liberated is 4.48 litres
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