anamalous behaviour of sodium
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smaal atomic and ionic size
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but I want at least two or three point
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Anomalous behaviour of sodium in
isotachophoresis
Abstract
Using a cationic operational system in
capillary isotachophoresis, millimolar
concentrations of sodium were determined
in the absence and presence of serum
proteins. With several internal standards,
the reproducibility of the sodium
determination was significantly poorer in
the presence of proteins, even after partial
thermal degradation. The results are
explained by protein—sodium interaction in
the injection port, where the electric field
strength was sixteen times lower than in
the separation capillary.
Anomalous behaviour of sodium in
isotachophoresis
Abstract
Using a cationic operational system in
capillary isotachophoresis, millimolar
concentrations of sodium were determined
in the absence and presence of serum
proteins. With several internal standards,
the reproducibility of the sodium
determination was significantly poorer in
the presence of proteins, even after partial
thermal degradation. The results are
explained by protein—sodium interaction in
the injection port, where the electric field
strength was sixteen times lower than in
the separation capillary.
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