Question

Aniline on heating with chloroform and ethanolic potassium hydroxide gives……. 

(a) Phenylisocyanide    (b)  Benzonitrile 

(c)     N‐methylaniline    (d)  Chlorobenzene​

Answer 1

Answer:

answer is

d. Chlorobenzene

Explanation:

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Answer 2

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Aniline, chloroform and alc. KOH  on heating gives foul smelling phenyl isocyanide.

anilineC6H5−NH2+CHCl3+3KOHheatPhenyl isocyanideC6H5−NC+3KCl+3H2O

This is Hoffmann's carbyl amines test also called isocyanide test. It is given by aliphatic or aromatic primary amines. This test is not indicated by secondary or tertiary amines.

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