anthracene on oxidation with sodium dichromate forms napthaquione
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chromic acid and sulfuric acid is oxidized to 1-2-anthraquinone; a reaction which would ordinarily easily oxidize the 9-10 position: in the central nucleus. and the hydro xyl groups in the 1-2 positions so stabilizes the central nucleus that it is not easily attacked.
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SODIUM DICHROMATE OXIDISES ANTHRACENE TO ANTHRAQUINONE.
Explanation:
- The oxidation reaction are those in which oxygen atoms get attached to the molecule.
- Sodium dichromate is an oxidizing agent(O.A).
- Anthracene is an aromatic ring, having 3 benzene rings attached to each other. Its formula is .
- When treated with sodium dichromate it oxidizes to form anthraquinone, the middle ring forms two C=O bonds.
- 9, 10 addition takes place as out of 3 rings, aromaticity is preserved in 2 rings, in other words aromatic sextet is preserved in 2 rings.
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