at 25 degree Celsius distance between two electrons in a conductivity cell is 1 cm and each electrode is of 2 cm square cross-section. this conductivity cell filled up with a solution containing 50 gram kcl per litre shows cell resistance 7.25 ohm. what is equivalent conductance of that solution?
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Answer:
Cell constant =Conductance of KClSp. cond. of KCl
=1/250.22.768×10−3
=2.768×10−3×250.2
For 0.01 M CuSO4 solution
Sp.conductivity=Cell constant×Conductance
=2.768×10−3×250.2×83311
Molar conductance =Sp.cond.×C1000
=83312.768×10−3×250.2×1/1001000=8.312 ohm−1cm2mol−1
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