At certain temperature, vapour pressure of pure element A and B has 108 and 36 torr respectively. If the solution has equal mole of A and B elements, then vapour pressure of solution is....
(A) 144 torr (B) 72 torr
(C) 90 torr
(D) 125 torr
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Answer:
(B) 72 torr
Given:
Let Moles of B=Moles of A=n
Mole fraction of B, Yb=(n/n+n)=1/2
Pa°=36 torr
Pb°=108 torr
Ptotal=Pa°+(Pb°-Pa°)Yb
=36+(108-36)*0.5
=36+72*0.5
=36+36
=72 torr
So, correct option is (B) 72 torr
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