Azulene have exceptionally high dipole moment due to
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In the various resonance structures for azulene, the most stable contributors put negative charge in the 5-membered ring and positive charge in the 7-membered ring.
In effect, this gives an aromatic 6 π-electron five-membered ring fused to an aromatic 6 π-electron seven-membered ring, as we see in the above diagram.
This separation of positive and negative charge gives the molecule a dipole moment of
1.08 D
Explanation:
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