(b) By electrophilic substitution
Aryl chlorides and bromides can be easily prepared by electrophilic
substitution of arenes with chlorine and bromine respectively in the
presence of Lewis acid catalysts like iron or iron(III) chloride.
CH3
CH3
CH3
Fe
+ X2
dark
X X
0-Halotoluene p-Halotoluene
+
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