Chemistry, asked by raviramraviram004, 1 year ago

Balanced equation for :ethyl chloride with alcoholic potassium hydroxide

Answers

Answered by kitty4846
1
Ethyl chloride can undergo both nucleophilic substitution as well as elimination reactions with strong alkali like KOH. 
When it undergoes nucleophilic substitution, ethyl alcohol is formed as major product.
 
Mechanism of nucleophilic substitution: 

Above mechanism depicts SN2 path. Usually primary alkyl halides show Nucleophilic bimolecular substitutions since the formation of carbocation is less easy. Hence bond breaking and making occurs in one step.
However, due to presence of β-hydrogen, ethyl chloride can also undergo elimination reaction to give ethylene in presence of strong base like KOH.
 
Since KOH is a strong base, it can also abstract β-hydrogen and thus by favoring elimination of HCl molecule (dehydrohalogenation).
Mechanism of dehydrohalogenation: 
The elimination of hydrogen halide may occur by E1 or E2mechanism. 
E1 path

E2 path

Since ethyl chloride is a primary alcohol, the preferred path is E2. 
Answer:
Now we can safely assume that:
i) When water is used as solvent, the likeliness of nucleophilic attack by H2O as well as OH- is more. That leads to formation of nucleophilic substituted product. 
ii) However in water, the elimination is not favored due to formation of water as one of the product. It is according to le Chatelier’s principle. Excess of water will shift the equilibrium to the left side.
iii) When the reaction is carried out in alcohol, less number of water molecules are available and thus by increasing the chances of attack of OH- ion on β-hydrogen.

vasimjalegar27: copied
raviramraviram004: i just asked equation!!!!!!
Answered by vasimjalegar27
2
Ethyl chloride can undergo both nucleophilic substitution as well as elimination reactions with strong alkali like KOH. 
When it undergoes nucleophilic substitution, ethyl alcohol is formed as major product.
 
C2H5Cl + KOH -----------》C2H5Oh + kcl
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