Benzene is less reactive than ethene and ethyne/towards addition because
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Both benzene and ethene are unsaturated hydrocarbons but benzene is less reactive than ethene due to extensive delocalization which causes stability. Benzene prefer substitution reactions over addition reaction.
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Ethyne is more reactive than ethene because it has two π-bonds which makes it weaker than ethane… ... In water the ethyne readily donates its H-atom . ...
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