Calculate the empirical and molecular formula of a compound containing carbon, 6.38%hydrogen and rest oxygen it's vapour density is 47.
Answers
Here is your answer:
You missed the composition of carbon
I have did this question in 11th
Carbon % = 76.5%
Hydrogen% = 6.38%
Oxygen% = 100 - (76.5 + 6.38)
= 100 - 82.88
= 17.12%
Now divide the percentage composition by the atomic mass of the element
For carbon: 76.5/12 = 6.38
For hydrogen: 6.38/1 = 6.38
For oxygen: 17.12/16 = 1.07
Now divide the answers you got to the least composition to a rough and nearest integer:
For carbon: 6.38/1.07 = 6
For Hydrogen: 6.38/1.07 = 6
For Oxygen: 1.07/1.07 = 1
Empirical Formula is C₆H₆O.
Empirical Formula Mass = 12 × 6 + 1 × 6 + 16
= 94 g
Molecular Mass = 2 × Vapor Density
∴ Molecular Mass = 2 × 47
∴ Molecular Mass = 94 g.
∴ n = Molecular Mass/Empirical Formula Mass
= 94/94
= 1
∴ Molecular Formula = 1 × C₆H₆O
= C₆H₆O
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