Calculate the freezing point of the solution when 31g of ethylene glycol (C2H6O2) is dissolved in 500g of water. (Kf for water = 1.86 K kg mol -1 )
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Answer : Given: 31 g of ethyene glycol is dissolved in 500g of water.
The freezing point of pure water is 273.15 K. On dissolving ethylene glycol, freezing point, being a colligative property, will be lowered.
AT= = K W × 1000 M.x W
We are given that
K+ for water=1.86 K kg mol-1
Mass of solute, w=31 g
Molar mass of solute, M, 2 x2 + 1x6+ 16 x 2
= 62 g mol-1
Mass of water, W=500 g
31 x 1000
.. AT = 1.86 ×
62 x 500
= 1.86 K
Hence, the freezing point of the solution,
Tf 273.15 K-1.86 K
= 271.29 K
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