calculate the total pressure( in ATM) of a mixture of 0.02 Mol of He(g) and 0.01 mole of H2(g) in 3 L flask at 127 °c
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The volume of the gas depends upon the number of moles only. They do not depend on the nature of the gas.
The mixture of gases have ,(0.2+0.3+0.4)= 0.9 mole.
The volume of the gaseous mixture at STP= 0.9 x 22.4= 20.16 litres.
The gaseous mixture is at
Temp= T=25°C=298K
Volume V =10 liters
Pressure=? At STP,
P° =1 atm
V°=20 .16 liters
T°=273
Now PV/T=P°V°/T°
So P= P° V°/T° x (T/V)
= (1 x 20.16 x 295)/(273 x 10)= 2.178 atm.
Partial Pressure of H2= 2/9 x 2.178=0.4356
Partial Press of N2=3/9 x 2.178= 0.6534
Partial Pressure of CH4=4/9 x 2.178=0.8712
The partial pressures of H2, N2 and CH4 are respectively 0.4356,0.6534 and 0.8712 atm
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