Chemical and photochemical reaction in smog formation
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The formation of photochemical smog involves three primary ingredients: nitrogen oxides, hydrocarbons and sunlight. The nitrogen oxides and hydrocarbons are by-products of fossil fuel-burning energy plants, and they can even come from natural processes, but the main source is the internal combustion engines in gasoline-powered automobiles.
Nitrous oxide and nitrogen dioxide dissociate in sunlight and combine with trace hydrocarbons to ultimately produce a large number of pollutants.
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