chloroform into diethylcarbonate
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It can be made by reacting phosgene with ethanol, producing hydrogen chloride as a byproduct. Because chloroform can react with oxygen to form phosgene, chloroform is stabilized for storage by adding 1 part (by mass) of ethanol to 100 parts (by mass) of chloroform, so that any phosgene that forms is converted into diethyl carbonate.
2 CH3CH2OH + COCl2 → CO3(CH2CH3)2 + 2HCl
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Because chloroform can react with oxygen to form phosgene, chloroform is stabilized for storage by adding 1 part (by mass) of ethanol to 100 parts (by mass) of chloroform, so that any phosgene that forms is converted into diethyl carbonate.
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