concentrated HNO3 used in laboratary work is 68% by mass in aqueous solution.find out molarity if density of solution is 1.504 gm/cm^3
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concentrated HNO3 used in laboratary work is 68% by mass in aqueous solution.find out molarity if density of solution is 1.504 gm/cm^3
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Solution :-
68 % m /m means 68 g of HNO3 (solute )in 100 g solution
- Solvent (H2O) = 100 - 68 = 32 g
- Density of solution = 1.504 g /cm³
Step I : Find moles of HNO3
- Mass of HNO3 (W)= 68 g
- Molar mass of HNO3 (M)= H + N + 3 (O) = 1 + 14 + 48 = 63 g
We know that ,
⇒ n = W / M
⇒ n = 68 / 63
⇒ n = 1.07
Step II : Volume of solution
- Mass of solution(m) = 100 g
- Density (d)= 1.504 g / cm³
we know that ,
⇒ d = m / v
⇒ v = m / d
⇒ v = 100 / 1.504
⇒ v = 66.4 cm³ / 66.4 mL
⇒ v = 0.066 L
Step III : Molarity
⇒ M = n / v
⇒ M = 1.07 / 0.066
⇒ M = 16.21 mol / L
The molarity of the solution is 16.21 M
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