Conditions for positive deviation from raoult's law
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hey. . itPositive deviations : ... In this type of deviations,the partial vapour pressure of solutions is less than that of ideal solution of same composition.Boiling point of such a solution is relatively higher than the boiling points of both the components.This type of behavior is known as negative
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Positive deviations from Raoult's Law
In mixtures showing a positive deviation from Raoult's Law, the vapour pressure of the mixture is always higher than you would expect from an ideal mixture. The deviation can be small - in which case, the straight line in the last graph turns into a slight curve.
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