Correct order of flocculating value of electrolytes KCl, K2SO4 and K3[Fe(CN)6] for coagulation of positive Fe(OH)3 sol is
Options:
KCl > K2SO4 > K3[Fe(CN)6]
KCl > K3[Fe(CN)6] > K2SO4
K3[Fe(CN)6] > KCl > K2SO4
K3[Fe(CN)6] > K2SO4 > KCl
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Answer:
KCl > K2SO4 > K3[Fe(CN)6]
Explanation:
Electrolyte of highest coagulating power has lowest flocculating value.
Fe(OH)3 is a positively charged sol and for its coagulation, order of flocculating value of given electrolytes is KCl > K2SO4 > K3[Fe(CN)6]
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The correct order of flocculating value of electrolytes KCl, K2SO4 and K3[Fe(CN)6] for coagulation of positive Fe(OH)3 sol Is KCl > K2SO4 > K3[Fe(CN)6].
- Coagulation value or flocculating value is the amount of electrolyte required to coagulate sol.
- Coagulation value is inversely proportional to coagulating power.
- The coagulation power is higher for higher oxidation states or higher charge species. it means the minimum amount of electrolyte required for coagulation has a maximum charge.
- KCl has -1, K2SO4 has -2 and K3[Fe(CN)6] has -3 on the anionic part.
- Fe(OH)3 is a positive sol and can be consulate by a negative sol.
- So, K3[Fe(CN)6] has the the the least value of coagulation.
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