Correct order of limiting molar conductivity of given ions in water at 298 Kis K+ > Nat > Mg2+ Mg2+ > K+ > Nat Mg2+ > Nat > K+ Na+ > K+ > Mg2+
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Explanation:
298 K is for (1) Mg+2
The limiting molar conductivity of is maximum for Mg+2 because limiting molar conductivity increases with decrease in concentration of ions.
Mg+2 has less volume which increases its ionic mobility in aqueous solution.
and therefore it has maximum Limiting molar conductivity in water among the given options.
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Explanation:
From Kohlrausch's law,
Molar conductivity of KCl=λo(K+)+λo(Cl−)=73.5+76.3=149.8
Molar conductivity of CaCl2=λo(Ca2+)+2×λo(Cl−)=119+(2×76.3)=271.6
Molar conductivity of K2SO4=2×λo(K+)+λo(SO42−)=2×73.5+160=307
So, limiting molar conductivity of electrolytes follow the order: KCl<CaCl2<K2SO4.
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