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Caloulate Z* (effective nuclear charge- Slater's rule) for 2s and 4s electrons.
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Finally subtract the value of S from Z to find the value of effective nuclear charge, Zeff. For example, Us the Lithium atom, then Z =3 (atomic number) and S = 1.7. Now put the variables in the formula to know the value of Zeff (effective nuclear charge).
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