Chemistry, asked by bawaprabh1112, 1 year ago

Deduce the relation between Cp and Cv.

Answers

Answered by priyankasundar
0

Answer:

Cp-Cv =nR

Explanation:

this is the answer.hope it helps

Answered by bestwriters
3

Relationship between \bold{C_p} and \bold{C_v} for an Ideal Gas:

The moral heat capacity of the gas at constant volume is denoted as \bold{C_v}.

The molar heat capacity of the gas at constant pressure is denoted as \bold{C_P}.

The amount of heat transfer in ideal gas is given by the formula:

\bold{Q = n C \Delta T}

At constant pressure P, heat transfer is given as:

\bold{Q_p = n C_p \Delta T}

\bold{Q_p = n C_p \Delta T = \Delta H \longrightarrow (1)}

∆H is change in enthalpy

Now, at constant volume V, heat transfer is given as:

\bold{Q_v = n C_v \Delta T}

\bold{Q_v = n C_v \Delta T = \Delta U \longrightarrow (2)}

∆U is change in internal energy

We know that for one mole (n=1) of an ideal gas,

\bold{\Delta H = \Delta U + \Delta (pV ) = \Delta U + \Delta (RT) = \Delta U + R \Delta T}

Therefore, \bold{\Delta H = \Delta U + R \Delta T}

Where R is gas constant

Substituting the values of ∆H and ∆U from equation (1) and (2), we get,

\bold{C_p \Delta T = C_v \Delta T + R \Delta T}

\bold{C_p = C_v + R}

Thus,

\bold{C_p - C_v = R}

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