Deduce the relation between Cp and Cv.
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Answer:
Cp-Cv =nR
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Relationship between and for an Ideal Gas:
The moral heat capacity of the gas at constant volume is denoted as .
The molar heat capacity of the gas at constant pressure is denoted as .
The amount of heat transfer in ideal gas is given by the formula:
At constant pressure P, heat transfer is given as:
∆H is change in enthalpy
Now, at constant volume V, heat transfer is given as:
∆U is change in internal energy
We know that for one mole (n=1) of an ideal gas,
Therefore,
Where R is gas constant
Substituting the values of ∆H and ∆U from equation (1) and (2), we get,
Thus,
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