define boyle's law with its mathematical expression
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BOYLE'S LAW
Robert Boyle studied the relationship between volume and pressure of a gas keeping the temperature constant. This relationship is named after him as Boyle's Law.
Boyle's law state that at constant temperature the volume of certain mass of a gas is inversely proportional to its pressure.
V α 1/P at a constant temperature, where V is the volume and P is the pressure. Introducing Proportionality constant K.
V = K/P or PV = K
→ At constant temperature, the product of pressure and volume of a given mass of gas is constant. If P₁ and P₂ are the initial and final pressures, V₁ and V₂ are initial and final volumes respectively at constant temperature.
P₁V₂ = P₂V₂
→ When pressure of gas is plotted against its volume at constant temperature for a fixed mass of gas, we get curves. The shape of the Boyle's Law curve is rectangular hyperbola.
→ Since the temperature is constant, Boyle's Law curves are called isotherms. When the product of pressure and volume is plotted against the pressure or volume, a straight line parallel to the pressure or volume, a straight line parallel to the pressure or volume axis is obtained.
NOTE:- Before deriving the Boyle's Law we need to derive Gas law from kinetic gas Equation.
Let's start deriving the ''Gas law from kinetic gas Equation.''
Change in momentum = Pbefore - Pafter
= mμx - (-mux)
= 2mux ------------->(1)
Velocity = Distance/time
= 2L/Δt = Δt = 2L/velocity = 2L/Ux --------------->(2)
Force = change in momentum/Δt = 2mux/2L/μx = mu²/L ------------>(3)
Pressure = Force/area
= mu²x/L × 1/area
= mux²/L × 1/L²
= mu²x/L²
P = mu²x/V
Now, Total Velocity u² = u²x + u²y + u²z
= (Ux = Uy = Uz)
= U² = U²x + U²x + U²x
= U² = 3U²x
= U²/3 = U²x --------->(4)
→ P = mu²x/V
→ P = mu²/3v
→ PV = 1/3mu²
Here, U and C ---> Velocity
→ PV = 1/3mc² → Kinetic Energy Gas Law
Now, we will derive Boyle's Law
→ PV = 1/3mc²
PV = 2/3×2 mc²
→PV = 2/3 (1/2mc²)
→ PV = 2/3 K.T
→ PV = 2/3 K.T
→ PV = Constant
Hope it helps you !
Here is your answer,
BOYLE'S LAW
Robert Boyle studied the relationship between volume and pressure of a gas keeping the temperature constant. This relationship is named after him as Boyle's Law.
Boyle's law state that at constant temperature the volume of certain mass of a gas is inversely proportional to its pressure.
V α 1/P at a constant temperature, where V is the volume and P is the pressure. Introducing Proportionality constant K.
V = K/P or PV = K
→ At constant temperature, the product of pressure and volume of a given mass of gas is constant. If P₁ and P₂ are the initial and final pressures, V₁ and V₂ are initial and final volumes respectively at constant temperature.
P₁V₂ = P₂V₂
→ When pressure of gas is plotted against its volume at constant temperature for a fixed mass of gas, we get curves. The shape of the Boyle's Law curve is rectangular hyperbola.
→ Since the temperature is constant, Boyle's Law curves are called isotherms. When the product of pressure and volume is plotted against the pressure or volume, a straight line parallel to the pressure or volume, a straight line parallel to the pressure or volume axis is obtained.
NOTE:- Before deriving the Boyle's Law we need to derive Gas law from kinetic gas Equation.
Let's start deriving the ''Gas law from kinetic gas Equation.''
Change in momentum = Pbefore - Pafter
= mμx - (-mux)
= 2mux ------------->(1)
Velocity = Distance/time
= 2L/Δt = Δt = 2L/velocity = 2L/Ux --------------->(2)
Force = change in momentum/Δt = 2mux/2L/μx = mu²/L ------------>(3)
Pressure = Force/area
= mu²x/L × 1/area
= mux²/L × 1/L²
= mu²x/L²
P = mu²x/V
Now, Total Velocity u² = u²x + u²y + u²z
= (Ux = Uy = Uz)
= U² = U²x + U²x + U²x
= U² = 3U²x
= U²/3 = U²x --------->(4)
→ P = mu²x/V
→ P = mu²/3v
→ PV = 1/3mu²
Here, U and C ---> Velocity
→ PV = 1/3mc² → Kinetic Energy Gas Law
Now, we will derive Boyle's Law
→ PV = 1/3mc²
PV = 2/3×2 mc²
→PV = 2/3 (1/2mc²)
→ PV = 2/3 K.T
→ PV = 2/3 K.T
→ PV = Constant
Hope it helps you !
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Shanaya200:
wow what an amazing explanation !superb
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