Define law of reciprocal proportion with example
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The law of reciprocal proportions was proposed by Jeremias Ritcher in 1792. It states that, "If two different elements combine separately with the same weight of a third element, the ratio of the masses in which they do so are either the same or a simple multiple of the mass ratio in which they combine."
Explanation:
For example -
Oxygen and sulfur react with copper to give copper oxide and copper sulfide, respectively. Sulfur and oxygen also react with each other to form SO2. Therefore,
in CuS:
Cu:S = 63.5:32
in CuO:
Cu:O = 63.5:16
S:O = 32:16
S:O = 2:1
Now in SO2:
S:O = 32:32
S:O = 1:1
Thus the ratio between the two ratios is the following:
2/1 : 1/1 = 2:1
This is a simple multiple ratio.
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