derive an expression for rate constant of first order reaction
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Explanation:
For a 1st order reaction: A→Products; the rate of reaction at [A]=0. 2M is 1×10−3 mol L−1s−1 reaction will be 75% completed in.
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Answer:
First-Order Reactions
A first-order reaction depends on the concentration of one reactant, and the rate law is: r=−dAdt=k[A] r = − dA dt = k [ A ] .
r=−d[A]dt=k[A]
2N2O5(g)→4NO2(g)+O2(g)
Rate=k[N2O5]m.
rate=k[N2O5]1=k[N2O5]
1.4×10−3=k(0.020)
k=0.070s−1.
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