Derive Nernst distribution equation, Mention its limitations and applications.
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When a solute is shaken with two non-miscible solvents, at equilibrium both the solvents are saturated with the solute. Since the solubility also represents concentration, we can write the distribution law as C1/C2 = S1/S2 = KD where S1 and S2 are the solubilities of the solute in the two solvents.