derive relation cp and cv
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CP. ...specific heat at constant pressure..
CV. .....specific heat at constant volume....
Hope it helps u☺
CV. .....specific heat at constant volume....
Hope it helps u☺
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Relationship between CP and CV for an Ideal Gas
From the equation q = n C ∆T, we can say:
At constant pressure P, we have qP = n CP∆T
This value is equal to the change in enthalpy, that is, qP = n CP∆T = ∆H
Similarly, at constant volume V, we have qV = n CV∆T
This value is equal to the change internal energy, that is, qV = n CV∆T= ∆U
We know that for one mole (n=1) of ideal gas,
∆H = ∆U + ∆(PV)
= ∆U + ∆(RT)
= ∆U + R∆T
Therefore, ∆H = ∆U + R ∆T
Substituting the values of ∆H and ∆U from above in the former equation,
C_P ∆T = C_V ∆T + R ∆T
Or,
Or,
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