Chemistry, asked by varanebrema, 1 year ago

Describe the fluorescent tube’s spectrum.

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Answered by amoghasrikara
5

A fluorescent lamp tube is filled with a gas containing low pressure mercury vapor and argon, xenon, neon, or krypton. The pressure inside the lamp is around 0.3% of atmospheric pressure.[23] The inner surface of the lamp is coated with a fluorescent (and often slightly phosphorescent) coating made of varying blends of metallic and rare-earth phosphor salts. The lamp's electrodes are typically made of coiled tungsten and usually referred to as cathodes because of their prime function of emitting electrons. For this, they are coated with a mixture of barium, strontium and calcium oxides chosen to have a low thermionic emission temperature.

A germicidal lamp uses a low pressure mercury vapor glow discharge identical to that in a fluorescent lamp, but the uncoated fused quartz envelope allows ultraviolet radiation to emerge.

Fluorescent lamp tubes are typically straight and range in length from about 100 millimeters (3.9 in) for miniature lamps, to 2.43 meters (8.0 ft) for high-output lamps. Some lamps have the tube bent into a circle, used for table lamps or other places where a more compact light source is desired. Larger U-shaped lamps are used to provide the same amount of light in a more compact area, and are used for special architectural purposes. Compact fluorescent lamps have several small-diameter tubes joined in a bundle of two, four, or six, or a small diameter tube coiled into a helix, to provide a high amount of light output in little volume.

Light-emitting phosphors are applied as a paint-like coating to the inside of the tube. The organic solvents are allowed to evaporate, then the tube is heated to nearly the melting point of glass to drive off remaining organic compounds and fuse the coating to the lamp tube. Careful control of the grain size of the suspended phosphors is necessary; large grains, 35 micrometers or larger, lead to weak grainy coatings, whereas too many small particles 1 or 2 micrometers or smaller leads to poor light maintenance and efficiency. Most phosphors perform best with a particle size around 10 micrometers. The coating must be thick enough to capture all the ultraviolet light produced by the mercury arc, but not so thick that the phosphor coating absorbs too much visible light. The first phosphors were synthetic versions of naturally occurring fluorescent minerals, with small amounts of metals added as activators. Later other compounds were discovered, allowing differing colors of lamps to be made.



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