difference between acidic strength order and acidity order
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Acid strength:
- Acid strength refers to the tendency of an acid, symbolised by the chemical formula HA, to dissociate into a proton, H⁺, and an anion, A⁻.
- The dissociation of a strong acid in solution is effectively complete, except in its most concentrated solutions.
Acid order:
- The relationship between conjugate basicity and acidity is an inverse one, so the order of acidity is: CH4 (weakest acid) < NH3 < H2O < HF (strongest acid).
- The actual pKa values agree with this prediction: CH4 pKa 51 (weakest acid), NH3 pKa 38, H2O pKa 15.7 and HF pKa 3.2.
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☑ The bond strength of an acid generally depends on the size of the 'A' atom: the smaller the 'A' atom, the stronger the H-A bond. When going down a row in the Periodic Table (see figure below), the atoms get larger so the strength of the bonds get weaker, which means the acids get stronger.
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