difference between bending and stretching
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The absorption of IR radiation causes bonds to stretch and bend. Stretches correspond to the increasing and decreasing of the bondlenghs within a molecule. Bends correspond to the increasing and decreasing of the angle between bonds in a molecule. The animations below show the possible vibrations of the H2O molecule.
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Bending vibrations change bond angles. A stretching vibration changes the bond length. In symmetric stretching, two or more bonds vibrate in and out together.
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