Difference between inert pair effect and shielding effect
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Inert Pair effect arises due to the tendency of outer s orbital to not take part in the bonding. Hence there is increase in stability of oxidation state lower down the group that is 2 less than the group oxidation state.
Shielding effect :If the electron is in s orbital, it means it is nearest to nucleus and if in f shell, it means it is farthest from nucleus. Since, atomic shielding depends on electron density in a orbital and electron density is very less for d and f orbitals, hence it has poor shielding effect as compared to s and p orbitals.
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