Disassociation energy formula ??
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- ꜱᴏʟᴠᴀᴛɪᴏɴ ɪꜱ ᴛʜᴇ ɪɴᴛᴇʀᴀᴄᴛɪᴏɴ ʙᴇᴛᴡᴇᴇɴ ꜱᴏʟᴠᴇɴᴛ ᴍᴏʟᴇᴄᴜʟᴇꜱ ᴀɴᴅ ᴛʜᴇ ɪᴏɴꜱ ᴏʀ ᴍᴏʟᴇᴄᴜʟᴇꜱ ᴅɪꜱꜱᴏʟᴠᴇᴅ ɪɴ ᴛʜᴀᴛ ꜱᴏʟᴠᴇɴᴛ. ᴛʜᴇ ʜᴏᴍᴏʟʏᴛɪᴄ ʙᴏɴᴅ ᴅɪꜱꜱᴏᴄɪᴀᴛɪᴏɴ ᴇɴᴇʀɢʏ ɪꜱ ᴛʜᴇ ᴀᴍᴏᴜɴᴛ ᴏꜰ ᴇɴᴇʀɢʏ ɴᴇᴇᴅᴇᴅ ᴛᴏ ʙʀᴇᴀᴋ ᴀᴘᴀʀᴛ ᴏɴᴇ ᴍᴏʟᴇ ᴏꜰ ᴄᴏᴠᴀʟᴇɴᴛʟʏ ʙᴏɴᴅᴇᴅ ɢᴀꜱᴇꜱ ɪɴᴛᴏ ᴀ ᴘᴀɪʀ ᴏꜰ ʀᴀᴅɪᴄᴀʟꜱ.
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Explanation:
CH3CH2–H → CH3CH2• + H•, DH°298(CH3CH2−H) = ΔH° = 101.1(4) kcal/mol = 423.0 ± 1.7 kJ/mol = 4.40(2) eV (per bond). To convert a molar BDE to the energy needed to dissociate the bond per molecule, the conversion factor 23.060 kcal/mol (96.485 kJ/mol) for each eV can be used.
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