discuss various methods of reduction of esters giving the products formed
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A new method for reduction of esters to aldehydes through silyl acetal intermediates involves a single‐step hydrosilylation catalyzed by a readily available iridium complex, [{Ir(coe)2Cl}2] (see scheme; coe=cyclooctene).
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♦♦♦♦♦♦♦♦♦♦♦♦♦♦♦♦♦♦♦♦♦♦♦♦♦♦♦♦
A new method for reduction of esters to aldehydes through silyl acetal intermediates involves a single‐step hydrosilylation catalyzed by a readily available iridium complex, [{Ir(coe)2Cl}2] (see scheme; coe=cyclooctene).
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Hope it helps u✌
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1. Generally, Esters are reduced to alcohols by reacting it with lithium aluminum hydride.
Example: Propyl ethanoate is reduced to propanol and ethanol.
2. Esters are reduced into aldehydes with help of di-isobutyl aluminum hydride (DIBAL).
3. Thioesters are reduced into aldehydes with a palladium catalyst and silyl hydride.
4. Esters are reduced to ethers with the help of Et3SiH. Here, the catalyst is InBr3.
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