Dissolve a substance of 0.900 g in 60.0 g water, to achieve the freezing point drop of 0.150 K, the molecular weight of the material is (water Kf = 1.86 K•kg/mol) :
Answers
THE MOLECULAR WEIGHT OF UNKNOWN SUBSTANCE DISSOLVED IN 60 gm OF WATER IS = 186 gm/mol
IT IS GIVEN THAT 0.900 gm OF UNKNOWN SUBSTANCE IS DISSOLVED IN 60 gm OF WATER
- The depression in freezing point is a colligative property that occurs when the molecules of solute are added into the solvent results in the lowering of freezing point and is given by ,
ΔTf= Kf × m
- where ΔTf= Tf(solvent)-Tf(solution) and m is molality
- According to given question,
- Weight of unknown substance dissolved= 0.90gm
- Weight of solvent(water)= 60.0 gm
- Depression in freezing point , ΔTf= 0.150 K Kf=1.86 K.KG/MOL
- LET M be the molecular weight of unknown substance
- molality , m= × =
- ΔTf= Kf × m = 1.86 × = 0.150
HENCE, the molecular weight of unknown substance is
186 g/mol
THANKS!!
Thus the molecular weight of unknown substance is 186 g/mol
Explanation:
The lowering of freezing point and is given by "ΔTf" = Kf × m
Where
- ΔTf = Tf (solvent) - Tf (solution)
- m = molality
According to given question
Weight of unknown substance dissolved= 0.90 g
Weight of solvent(water) = 60.0 g
Depression in freezing point "ΔTf" = 0.150 K
Kf = 1.86 K.Kg / mol
LET M be the molecular weight of unknown substance
Molality , m = 0.9 / M × 1000 / 60 = 5 / M
ΔTf = Kf × m = 1.86 × 15 / M = 0.150
Thus the molecular weight of unknown substance is 186 g/mol