Electrolytic conductance generally decreases
with rise in temperature.
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The electrical resistance (and conductance) of a material changes with temperature. For different type of materials, the amount and direction of this change is different (refer to the attached figure). In case of electrolytes, insulators and semiconductors the resistance of the material decreases with rise in temperature.
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In metals, thermal conductivity decreases with increase in temperature. Metals have abundance of free electrons and they have considerable lattice vibrations, so in normal condition they conduct smoothly.
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