Enthalpy departure derivation
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Enthalpy departure is the dimensionless value of (h[ideal]-h)/(RTc). h[ideal]-h is the difference in enthalpy between an ideal gas and a real gas at the same temperature and pressure. R is the gas constant and Tc is the critical temperature.
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Common departure functions include those for enthalpy, entropy, and internal energy. ... A departure function gives the difference between the real state, at a finite volume or non-zero pressure and temperature, and the ideal state, usually at zero pressure or infinite volume and temperature.
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