Equation of blue copper solution and later iron rusted and solution becomes green reason
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Fe + CuSO4 -------> Cu + FeSO4
Iron Copper sulphate Copper Iron sulphate
The highly reactive iron displaces copper from the copper sulphate solution. Therefore you can observe that after few minutes when an iron nail is dipped in the copper sulphate solution, the copper particles are placed on the iron nail and the copper sulphate solution(blue) changes to iron sulphate solution(green).
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