equivalent mass of H3PO2 when it disproportionates into PH3 and H3PO3 is
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M/4
- H3PO2 ---------------->H3PO3+PH3
- oxidation state of H3PO2 is 1 and +3in PH3 and H3PO3
- change in oxidation state is 2 for both the cases and hence equivalent weight is M/4
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