explain action of sodium bisulfite on methanal
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NUCLEOPHILIC ADDITION IN ALDEHYDES AND KETONES - DEFINITION

The aldehydes and ketones undergo nucleophilic addition reactions. Mechanism of Nucleophilic addition is:
A nucleophile attacks the electrophilic carbon atom of the polar carbonyl group from a direction approximately perpendicular to the plane of sp2 hybridised orbitals of carbonyl carbon.
The hybridisation of carbon changes from sp2 to sp3 and a tetrahedral alkoxide intermediate is produced.
This intermediate captures a proton from the reaction medium to give the electrically neutral product.
The net result is addition of Nu− and H+ across the carbon oxygen double bond.
IMPORTANT NUCLEOPHILIC ADDITION REACTONS OF ALDEHYDES AND KETONES - DEFINITION
Addition of hydrogen cyanide (HCN)
Addition of sodium hydrogensulphite
Addition of Grignard reagents
Addition of alcohols
Addition of ammonia and its derivatives
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