explain anomalous behaviour of lithium
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Anomalous behaviour of Lithium is due to. 1) very small size of lithium atom and its ions. 2) higher polarising power of Li + resulting in increased covalent character of its compounds which is responsible for their solubility in organic solvents.........
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Answer:
Lithium shows anomalous behaviour due to:
- Small size
- Low ionization enthalpy
- Absence of vacant d orbitals
Anomalous behaviours are:
- Lithium is much harder(melting point and boiling point is high)
- Lithium form monoxide while others form peroxide and superoxide
- Lithium react with nitrogen to form Lithium nitride while other alkali metals do not form nitrides.
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