Explain Baker Nathan's effect. On the basis
of it give stability of carbocation
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In organic chemistry, the Baker–Nathan effect is observed with reaction rates for certain chemical reactions with certain substrates where the order in reactivity cannot be explained solely by an inductive effect of substituents. This effect was described in 1935 by John W. Baker and W. S. Nathan.
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Explanation:
BAKER-NATHAN EFFECT (or) HYPERCONJUGATION (or) NO BOND RESONANCE.
- Hyperconjugation is the process of delocalizing -electrons or a lone pair of electrons into an adjacent -orbital or p-orbital.
- It happens when a -bonding orbital or an orbital with a lone pair overlaps with a neighboring -orbital or p-orbital.
- As we progress from primary to secondary to tertiary carbons, the stability of carbocations improves.
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